A usual, the definition part of the clue is underlined, except for double definition and cryptic definition clues.
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1. Eggs it's nice to scramble (7) = INCITES
The definition is a nice confusion here — it's a verb, as in egging on someone, not a noun! Anagram indicated by scramble of it's nice. Ignore that apostrophe.
4. It's mean to the players (5) = MEZZO
Cryptic definition. MEZZO is a musical term meaning 'middle'. Mean is an average, or the middle. So MEZZO is a term that means 'middle' to musicians (players).
7. A stake in a buoyant economy (4) = ANTE
Hidden word clue, indicated by in. You can see it in buoyant economy.
8. On the edge and somewhat alarming (8) = MARGINAL
Anagram, indicated by somewhat, of alarming.
10. He draws actors into trouble (10) = CARTOONIST
Anagram clue. Actors into is the anagram fodder, trouble is the anagram indicator. The definition is pretty broad – a lot of other people draw too!
12. Mafia activity produces terrible row (6) = RACKET
Double definition. The two definitions are Mafia activity and terrible row (as in noise).
13. Reason to stop flying (6) = GROUND
Cryptic definition — the ground is definitely a good reason to stop flying!
15. Agree on a definition of 24 hours and finish work (4,2,1,3) = CALL IT A DAY
Double definition. The definitions are separated by and.
18. A collection of letters (8) = ALPHABET
19. A mother for one who was motherless (4) = ADAM
Biblical cryptic definition. Refers to Eve being created from Adam's rib.
20. Not an irreversible belief (5) = TENET
Palindromic cryptic definition. Nice double negative in there —not an irreversible means that it is reversible! Could be &lit, I think ... as a TENET is a main principle, so I think it would be fair to say it's not an irreversible belief, as the definition. Reading the clue again literally provides the definition, in addition to reading it as wordplay.
21. Review on thug's weapon (7) = SHOTGUN
Anagram of on thug's, indicated by review.
1. Is a short account for a patriarch (5) = ISAAC
Charade clue. Is a= IS A (in the clear!) + AC (short account). You need a little Biblical knowledge to get this one.
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Double definition — a cataract is a waterfall (which produces water spray), and an eye condition that reduces visibility.
3. Yields a chessman on board (6) = SPAWNS
Container clue. A chessman = PAWN is put on (inside) of SS (on board a ship).
4. One who is just sitting on a bench (10) = MAGISTRATE
Cryptic definition. Just means fair / objective here, and the bench refers to the law court.
5. Something final to any buffoon (4) = ZANY
Charade clue. Something final= Z (the final letter of the alphabet) + any(in the clear). A buffoon is a noun, and modern usage of ZANY is as an adjective. But there is a historical definition of zany meaning a zany person. So it's an unusual definition.
6. Did favours when compelled? (7) = OBLIGED
Double definition, with very similar definitions, so I think this is a poor clue. These two definitions come under the same headword and have the same etymology.
9. Very different from divorces in Warsaw? (5,5) = POLES APART
Double definition, with a coined meaning from divorces in Warsaw.
11. An animal looking for his master (5,3) = GUIDE DOG
Clever cryptic definition! Actual meaning is an animal seeing for his master.
12. Run into some of the defence (7) = RAMPART
Charade clue. Run into = RAM + some of = PART
14. Is inactive in retirement? (6) = SLEEPS
Cryptic definition. Retiring for the night, not retiring from work.
16. Potential enemy country (5) = YEMEN
Anagram of enemy, indicated by potential.
17. Twisted point to a witticism (4) = SPUN
A charade clue. Point = S (south) + a witticism = PUN.